Product Code: 4502

Devarda’s Alloy, Reagent Grade

Lead-free20–100 Mesh Granules Nitrogen Determination in Fertilizers and Soils Reagent Grade Standard Nitrate Reducing Agent
Devarda's Alloy (50% Cu, 45% Al, 5% Zn), reagent grade, 20–100 mesh. The standard reducing agent for nitrate and nitrogen determination.
Solidus
1,000°F (538°C)
Liquidus
1,090°F (588°C)
Density
0.152 lbs/in³ (4.2 g/cm³)
Primary Elements
Zn, Al, Cu
Nominal Composition
45% Al, 5% Zn, 50% Cu
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Product Overview

Devarda’s Alloy is a copper-aluminum-zinc alloy with a nominal composition of 50% Cu, 45% Al, and 5% Zn, supplied as reagent grade 20–100 mesh granules. It is a powerful reducing agent in alkaline solution and has been the standard reagent for reducing nitrates to ammonia since it was introduced in the 1890s.

In analytical chemistry, Devarda’s alloy is used to determine nitrate and total nitrogen in fertilizers, soils, water, and other samples. In alkaline solution the alloy reduces nitrate and nitrite to ammonia, which is then distilled and measured. It is also used in qualitative tests for nitrate in teaching laboratories.

The 20–100 mesh particle size provides a fast, complete reaction while remaining easy to weigh and dispense.

Available Forms

20-100 Mesh Granular

Product Code

4502

Technical Info

Thermal Properties

Melting Point (Solidus)1,000°F (538°C)
Melting Point (Liquidus)1,090°F (588°C)

Physical Properties

Density (imperial)0.152 lbs/in³
Density (metric)4.2 g/cm³
Primary ElementsZn, Al, Cu
Lead FreeYes
Key Features
20–100 Mesh GranulesNitrogen Determination in Fertilizers and SoilsReagent GradeStandard Nitrate Reducing Agent
Solubility Note

Reacts with alkaline solutions to generate hydrogen, store sealed, dry, and away from acids and bases.

Nominal Composition

  • 50% Cu
  • 45% Al
  • 5% Zn
It is used to reduce nitrate and nitrite to ammonia in alkaline solution. This is the basis of the Devarda method for determining nitrate and total nitrogen in fertilizers, soils, plant tissue, and water. It is also used in qualitative nitrate tests in teaching laboratories.
In a sodium hydroxide solution, the aluminum and zinc in the alloy react to produce hydrogen, which reduces nitrate and nitrite ions to ammonia. The copper helps the reaction proceed smoothly. The ammonia is then distilled off and measured by titration.
Keep the container tightly closed in a dry place away from acids, bases, and moisture. The alloy reacts with water and alkaline solutions to generate flammable hydrogen gas. Refer to the Safety Data Sheet for handling guidance.

Safety Data (SDS)

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